Heterogeneous nickel isotope compositions of the terrestrial mantle – Part 2: Mafic lithologies

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چکیده

We report stable Ni isotope compositions (?60/58Ni, relative to SRM986) for mafic lavas with a range of ?0.16‰ +0.20‰ (n = 44), similar that peridotite samples. Ocean island basalts (OIB) have been analysed from Iceland 6), the Azores 3), Galápagos Islands 2), and L??ihi, Hawaii 1). Samples (average ?60/58Ni +0.13 ± 0.16‰, 2s, n 7) display greatest in single OIB location this work, +0.01‰ +0.23‰. ?0.10 0.10‰, 2s) ?0.01 0.04‰, are generally isotopically lighter. The L??ihi sample has +0.17‰. lightest bulk rock ?0.16‰, is island, Pico. Enriched mid ocean ridge (E-MORB), which (La/Sm)N > 1, lighter than normal type MORB (N-MORB), as shown by data Mid Atlantic Ridge 9) East Pacific Rise 3). All E-MORB average +0.00 0.06‰ (2s, 7), whereas N-MORB +0.14 0.10‰ 5). A suite 15 samples Cameroon Line, comprising lithologies ranging nephelinites hypersthene-normative basalts, identical within analytical uncertainty +0.08 0.06‰, 2s). Similarly, no relationship between geochemical indicators degree partial melting or fractional crystallisation. Host two previously ultramafic xenolith suites their respective suites. This consistent published evidence peridotites komatiites isotopes not greatly fractionated melting. Therefore, rocks may preserve mantle source. Sampling greater volume mantle, composition +0.07 0.17‰ 44) also be better representation Bulk Silicate Earth (BSE), estimates based purely on peridotites. co-varies La/Sm, Rb/Sr, europium anomaly (Eu/Eu*), K2O/(K2O + Na2O). relationships these parameters mixing model endmembers. One could depleted (DMM) relatively heavy composition; other more enriched endmember ?60/58Ni. link further supported light associated some pyroxenite xenoliths. However, curvature apparent arrays defined hard reconcile admixing geochemically but oceanic crustal lithologies. High [Ni] magmas such kimberlites closer match endmember. needs study.

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ژورنال

عنوان ژورنال: Geochimica et Cosmochimica Acta

سال: 2022

ISSN: ['1872-9533', '0016-7037']

DOI: https://doi.org/10.1016/j.gca.2021.11.011